Open this publication in new window or tab >>2013 (English)In: Fuel, ISSN 0016-2361, E-ISSN 1873-7153, Vol. 113, p. 248-256Article in journal (Refereed) Published
Abstract [en]
Bitumen is a complex hydrocarbon whose composition-structure-property relationship is not well-understood. In this paper, microphase-separated topographic morphologies of unaged penetration grade 70/100 bitumen binders have been visualized by means of AFM QNM, and the relationship to local mechanical properties has been demonstrated. AFM QNM is a surface force mapping technique which measures parameters such as topography, adhesion and elastic modulus simultaneously. The resulting data can then be presented as images representing individual or overlaid parameters, e. g. topographic images with an adhesion overlay or topographic images with a modulus overlay. AFM QNM results show that the adhesive forces measured in the region surrounding (peri phase) the periodic topographic features resembling 'bees' (catana phase) and the region in the 'bee' areas are lower than the adhesive force measured in the smooth matrix (para phase). Likewise it was observed that Young's moduli in the region surrounding (peri phase) the 'bees' (catana phase) and in the 'bees' are higher than Young's modulus of the smooth matrix (para phase).
Keywords
Bitumen, AFM, Adhesion, Young's modulus, Topography
National Category
Engineering and Technology
Research subject
FOI-portföljer, Äldre portföljer
Identifiers
urn:nbn:se:trafikverket:diva-5870 (URN)10.1016/j.fuel.2013.05.042 (DOI)000323937300029 ()2-s2.0-84879473761 (Scopus ID)
Projects
T7729T7736Oberoende mätning av polära och dipolära krafter hos bitumen
Funder
Swedish Transport Administration, TRV 2012/53213
Note
QC 20130320. Updated from submitted to published.
2023-02-212023-02-212025-09-04